Potentiometry is one of the most convenient and successful technique employed for metal complex equilibrium measurements. In the present work, the interactions of transition metal ions Mn(II) and Co(II) with 5-ASA has been investigated in double distilled water mixture at 0.2 M ionic strength at temp 30 °C + 1.00C by potentiometrically. Proton ligand (pK) and metal-ligand (logK) stability constant were determined by using Calvin Bjerrum titration technique as modified by Irving & Rossoti.
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