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Polymer Congress 2018

Polymer Sciences

ISSN: 2471-9935

Page 76

June 04-05, 2018

London, UK

4

th

Edition of International Conference on

Polymer Science and

Technology

Polym Sci 2018, Volume 4

DOI: 10.4172/2471-9935-C2-012

T

heRECYSITEproject aims todevelopbio-sourcedcomposite

materials based on vegetal fibers and resins based on

humins and epoxidized linseed oil (ELO). In turn these materials

will be used as parts in the transportation and constructions

sectors. Humins are a by-product of bio-refineries in the

production of furan-based monomers. As a by-product, they

can represent as much as 30% w/w in the industrial process.

From a chemical standpoint they are complex mixtures of furan

derivatives, in various degrees of polymerization. This aspect

offers perspectives towards higher value applications such as

polymers. ELO is an epoxidized vegetable oil containing 5.5

oxirane moieties per molecule. It is regarded as a bio-sourced,

renewable alternative to classical, synthetic epoxides. Resins

were produced from humins, ELO and Capcure 3-800 and

characterized through ATR (Attenuated total reflection)

FT-IR (Fourier transform infrared spectroscopy). Based on

formulation, a wide array of materials was obtained with shore

hardness varying from 56A to 66D. The thermal behavior of the

resins was evaluated through differential scanning calorimetry

and thermogravimetric analysis. Composites, employing as

reinforcement, five types of vegetal fibers were obtained. The

adherence of the resin to the reinforcement was evaluated

through scanning electron microscopy (SEM) and was found

to be optimal. Figure 1 displays the results of the project. The

obtained composites present a bio-based content up to 85%.

The mechanical properties of the materials can be adjusted

by adapting the formulation. The good compatibility between

the resin and the reinforcement proposes the materials as

candidates to replace classical materials in applications.

At this moment, the materials are tested as parts for the

transportation and constructions sectors.

erol-dan.licsandru@unice.fr

Integration of industrial by-products into bio-sourced resins

and composites

Erol Dan Licsandru

1

, Monika Rymarczyk

2

, Aratz Genua

3

, David Ponce

4

and

Alice Mija

1

1

Institute of Chemistry of Nice, France

2

Centexbel, Belgium

3

Cidetec, Spain

4

AITIIP Technology Center, Spain