

Polymer Chemistry 2018
Polymer Sciences
ISSN: 2471-9935
Page 31
March 26-28, 2018
Vienna, Austria
3
rd
Edition of International Conference and Exhibition on
Polymer Chemistry
I
n this presentation, we introduce our recent accomplishments
on the integration of tailor-designed polymers for diverse
applications. Hybrid plasmonic nanostructures comprising Au
nanoparticle arrays separated from Au substrate through a
temperature-sensitive poly(N-isopropylacrylamide) linker layer
were constructed, and a unique plasmonic-coupling-based
surface plasmon resonance sensing properties and visible
light active photocatalysis were investigated. Multimetallic
Core@Shell nanoparticles consisting of Au core and metal-
containing polyaniline shells were prepared and their bifunctional
electrocatalytic performance was systematically investigated.
Well-defined ordered arrays of plasmonic nanostructures were
fabricated on stretchable poly(dimethyl siloxane) substrates
and tunable plasmon-coupling-based sensing properties were
comprehensively demonstrated upon extension and contraction.
We studied phosphorescence emission enhancement of a purely
organic phosphor system via plasmon resonance energy transfer
by precisely tuning the distance between purely organic phosphor
crystals and plasmonic nanostructures using layer-by-layer
assembled polyelectrolyte multilayers as a dielectric spacer. We
demonstrate a viable laser interference lithography technique
enabling the development of high-performance plasmonic organic
photovoltaic (OPV) devices. Ag nanodot arrays with optimized
configuration embedded in poly(3,4-ethylenedioxythiophene):pol
y(styre-esulfonate) hole transport layer remarkably enhanced the
average power conversion efficiency by ~34.4% compared to the
pristine device. Hierarchically organized porous carbonized-Co
3
O
4
inverse opal nanostructures were synthesized via complementary
colloid and block copolymer self-assembly, where the triblock
copolymer Pluronic P123 acts as the template and the carbon
source. These highly ordered porous inverse opal nanostructures
with high surface area display synergistic properties of high energy
density and promising bifunctional electrocatalytic activity toward
both the oxygen reduction reaction and oxygen evolution reaction
in Li-air battery.
Recent Publications:
1. Seol A Cho, Yu Jin Jang, Hee-Dae Lim, Ji Eun Lee,
Yoon Hee Jang,
et al.
(2017) Hierarchical porous
carbonized Co
3
O
4
inverse opals via combined block
copolymer and colloid templating as multifunctional
electrocatalysts and cathodes in Li-O
2
battery. Adv.
Energy Mater DOI: 10.1002/aenm.201700391.
2. Ji-Eun Lee, Yu Jin Jang, Wenqian Xu, Zhenxing Feng,
Hee-Young Park,
et al.
(2017) PtFe catalysts supported
on electroactive Au-PANI Core@Shell nanoparticles
for high-performance electrocatalysis. J. Mater.
Chem. A 5:13692−13699.
3. Yulin Oh, Ju Won Lim, Byung-Hyun Kang, Young Wook
Park, Heejun Kim,
et al.
(2016) Plasmonic periodic
nanodot arrays via laser interference lithography for
organic photovoltaic cells with >10% efficiency. ACS
Nano 10(11):10143–10151.
4. Ji-Eun Lee, Jumi Lee, Kyungwha Chung, Kwanwoo
Shin, Dong Ha Kim,
et al.
(2015)
In situ
studies of
surface plasmon resonance coupling sensor mediated
by stimuli-sensitive polymer linker. Adv. Funct. Mater.
25(18):6716–6724.
5. Minji Yoon, Ji-Eun Lee, Ju Won Lim, Saji Thomas
Kochuveedu, Yu Jin Jang,
et al.
(2015) Comprehensive
study on the controlled plasmon-enhanced
photocatalytic activity of hybrid Au/ZnO systems
mediated by thermoresponsive polymer linkers. ACS
Appl. Mater. Interf. 7(38):21073–21081.
Biography
Dong Ha Kim is currently a Full Professor and Ewha Fellow in the Department of
Chemistry and Nano Science of School of Natural Sciences at Ewha Woman’s Uni-
versity and Fellow of the Royal Society of Chemistry. He has authored 145 SCI pub-
lications and holds 29 registered Korean and two US patents. He is serving as Asso-
ciate Editor of Science of Advanced Materials (American Scientific Publishers), Edi-
torial Board Member of Scientific Reports (Nature Publishing Groups) and Advisory
Board Member of Nanoscale and J. Mater. Chem. (Royal Society of Chemistry). His
research interests include development of multi-functional hybrid nanostructures for
applications in energy storage and conversion, environmental remediation, memory
devices, display devices, and biomedical diagnosis/therapy, surface plasmon reso-
nance mediated theranostics, optoelectronics, photocatalysis and light emission.
dhkim@ewha.ac.krAdvanced optoelectronic materials and devices via
integrating functional polymers
Dong Ha Kim
Ewha Womans University, South Korea
Dong Ha Kim, Polym Sci, Volume 4
DOI: 10.4172/2471-9935-C1-008